Baeyer-Villiger oxidation converts ketones to what type of compound?

Unlock all questions

This demo includes only 20 questions. Upgrade to access hundreds of questions, flashcards, exam simulations, and disable ads.

Full question bankExam simulationsFlashcards
From $24.99Unlock all

Prepare for the AIChE Chemical Engineering Jeopardy Exam. Enhance your skills with challenging questions, detailed explanations, and exam-ready strategies. Be confident on exam day!

Multiple Choice

Baeyer-Villiger oxidation converts ketones to what type of compound?

Explanation:
Baeyer-Villiger oxidation inserts an oxygen atom into the carbonyl system, converting a ketone into an ester. When a ketone meets a peracid such as mCPBA, the peroxide adds to the carbonyl to form a Criegee intermediate, and one of the substituents on the carbonyl migrates to the adjacent oxygen. This rearrangement yields an ester as the main product (R-CO-O-R'), with the organic group that migrates influencing which ester forms if the ketone is unsymmetrical. For cyclic ketones, the reaction expands the ring by one carbon to give a lactone.

Baeyer-Villiger oxidation inserts an oxygen atom into the carbonyl system, converting a ketone into an ester. When a ketone meets a peracid such as mCPBA, the peroxide adds to the carbonyl to form a Criegee intermediate, and one of the substituents on the carbonyl migrates to the adjacent oxygen. This rearrangement yields an ester as the main product (R-CO-O-R'), with the organic group that migrates influencing which ester forms if the ketone is unsymmetrical. For cyclic ketones, the reaction expands the ring by one carbon to give a lactone.

More Multiple Choice Questions
Subscribe

Get the latest from Examzify

You can unsubscribe at any time. Read our privacy policy